Before you introduce yourself to the techniques of soapmaking, you need to understand what is soap.What is soap?

Today, everything what cleans is called soap, but majority of what you find in your grocery store is a mix of different surfactants – surface active chemicals that are able to clean.

 

But soap as we understand it in home made soapmaking is something different. Yes, it is also a type of surfactant, but a special one.

Chemically, it is a metal salt of fatty acids – do not panic, I will explain. 

 

Salt is a product of a reaction of an acid and a base.

Like the kitchen salt  (NaCl) is a product of reaction of HCl (hydrochloric acid) and NaOH (sodium hydroxide – base).

Although both of the two are highly corrosive and dangerous, their reaction produces NaCl – sodium chloride – aka kitchen salt – and water (H2O), which are both safe substances.

 

Similar thing happens when we make home made soap.

How is soap made?

 

Soap is made from fats/oils (acid) and lye (base – NaOH or KOH dissolved in water) by the reaction called saponification.

 

Vegetable/animal fats and oils are composed mainly of fatty acids.

 

These fatty acids there are attached (usually) by two or three to a molecule of glycerine.

This big molecule is called triglyceride. Oils also contain some free (not attached to the glycerine) fatty acids – this is important to know when making soap.

 

The reaction of saponification can be written as follows:

Chemical equation of saponification

 

You can see that if one molecule of triglyceride contains three fatty acids (R-COOH, where R stands for long carbon chain – which is a long chain of carbon and hydrogen molecule of different length), we need three molecules of sodium hydroxide (NaOH) to make three molecules of soap.

 

As a byproduct, one molecule of glycerine is produced.

 

In the industry, glycerine is extracted – it is a valuable ingredient used in pharma and cosmetics.

In a homemade process, glycerine stays in soap – and it is one of the main reasons, why homemade soap is so different.

This way, glycerine can make up to 25% of soap composition, although the percentage is lower if the soap water contain is taken into account.

 

What else contains homemade soap?

 

Oils and fats contain also other compounds, that are not fatty acids and cannot be converted into soap. These are called therefore insaponifiables.For example vitamins, phytosterols…

 

Good news is that all of these are left in the soap. Not all, though, do survive alkaline conditions – and one of my interests is to find, what happens with all insaponifiable goodies in the presence of lye solution…